Phone/Fax: +86 (0) 592-2187879
E-mail: xjkong@xmu.edu.cn
Education:
Selected Recent Publications:
1) Chen, J.-N.; Huang, K.-X.;Cheng, P.-M.; Qi, M.-Q.; Xu, H.; Chen, J.; Duan, Y.; Kong, X.-J.;* Zheng, L.-S.; and Long, L.-S.* Strong NIR-II Magneto-Optical Activity ofa Chiral Sm15Cu54 Cage J. Am. Chem. Soc. 2024,146, 22913−22917.
2) Li, C.-Y.;# Adi, L.C.;#Paillot, K.; Breslavetz, I.; Long, L.-S.; Zheng, L.-S.; Rikken, G. L. J. A.; Train, C.; Kong, X.-J.;* and Atzori, M.* Enhancement ofMagneto-Chiral Dichroism Intensity by Chemical Design: The Key Role ofMagnetic-Dipole Allowed Transitions J. Am. Chem. Soc. 2024,146, 16389−16393.
3) Du, M.-H.; Dai, Y.; Jiang, L.-P.; Su, Y.-M.; Qi, M.-Q.; Wang, C.;* Long, L.-S.;Zheng, L.-S.; Kong, X.-J.* Exploration and Insights on Topology Adjustment of Giant HeterometallicCages Featuring Inorganic Skeleton Assisted by Machine Learning J. Am. Chem. Soc. 2023, 145,23188−23195.
4) Li, C.-Y.; Xu, H.; Cheng, P.-M.; Du, M.-H.; Long, L.-S.;Zheng, L.-S.; Kong, X.-J.* From Helices to Crystals: Multi-Scale Representation of Chirality inDouble-Helix Structures J. Am. Chem. Soc. 2023, 145,22176-22183.
5) Chen, C.-L.; Wang, C.; Zheng, X.-Y.; Zhang, R.;* Xu, Y.; Zhuang, G.-L.; Long, L.-S.;Zheng, L.-S.; Kong, X.-J.;* Cao, Y* Conductive Lanthanide Metal-Organic Frameworks with ExceptionallyHigh Stability J. Am. Chem. Soc. 2023, 145,16983−16987.
6) Wang, X.; Wang,; S.-Q.; Chen, J.-N.; Jia, J.-H.; Wang, C.; Paillot, K.;Breslavetz, I.; Long, L.-S.; Zheng, L.-S.; Rikken, G. L. J. A.; Train, C.; Kong, X.-J.;* Atzori, M.* Magnetic 3d-4fChiral Clusters Showing Multi-Metal Site Magneto-Chiral Dichroism J.Am. Chem. Soc. 2022, 144, 8837–8847.
7) Du, M.-H.; Chen, L.-Q.; Jiang, L.-P.; Liu, W.-D.; Long, L.-S.;Zheng, L.-S.; Kong, X.-J.* Counterintuitive Lanthanide Hydrolysis-Induced Assembly Mechanism J.Am. Chem. Soc. 2022, 144, 5653-5660.
8) Du, M.-H.; Wang, D.-H.; Wu, L.-W.; Jiang, L.-P.; Li, J.-P.; Long, L.-S.;Zheng, L.-S.; Kong, X.-J.* Hierarchical Assembly of Coordination Macromolecules with AtypicalGeometries: Gd44Co28 Crown and Gd95Co60Cage Angew. Chem. Int. Ed. 2022, 61, e202200537;
9) Du, M.-H.; Xu, S-H.; Li, G.-J.;Xu, H.; Lin, Y.; Liu, W.-D.; Long, L.-S.; Zheng, L.-S.; Kong, X.-J.* Modification of Multi-Component Building Blocks for AssemblingGiant Chiral Lanthanide–Titanium Molecular Rings Angew. Chem. Int. Ed. 2022, 61, e202116296.
10) Pan, Z.-H.; Weng, Z.-Z.; Kong, X.-J.;* Long, L.-S.; Zheng, L.-S. Lanthanide-containing clusters for catalytic water splittingand CO2 conversion Coord. Chem. Rev. 2022,457, 214419;
11) Chen, R.; Zhuang, G.-L.; Wang,Z.-Y.; Gao, Y.-J.; Li, Z.; Wang, C.; Zhou, Y.; Du, M.-H.; Zeng, S.; Long,L.-S.; Kong, X.-J.;* Zheng, L.-S. Integration ofBio-Inspired Lanthanide-TransitionMetal Cluster and P-doped Carbon Nitride forEfficient Photocatalytic Overall Water Splitting Natl. Sci. Rev 2021, 8, nwaa234.
12) Du, M.-H.; Zheng,X.-Y.; Kong, X.-J.;* Long, L.-S.;* Zheng, L.-S. Synthetic Protocol for Assembling GiantHeterometallic Hydroxide Clusters from Building Blocks: Rational Design andEfficient Synthesis Matter 2020, 3, 1334–1349.
13) Zheng, X.-Y.; Xie, J.; Kong, X.-J.;* Long, L.-S.;* Zheng, L.-S. Recent advances inthe assembly of high-nuclearity lanthanide clusters. Coord. Chem. Rev. 2019, 378, 222-236.
14) Chen, R.; Yan, Z-H.; Kong, X.-J.;* Long, L.-S.; Zheng, L.-S.Integration of Lanthanide–Transition-Metal Clusters onto CdS Surfaces forPhotocatalytic Hydrogen Evolution. Angew.Chem. Int. Ed. 2018, 57,16796 –16800.
15) Yan, Z-H.; Du, M.-H.; Liu, J.; Jin, S.; Wang, C.; Zhuang, G.L.; Kong, X.-J.;* Long, L.-S.; Zheng, L.-S.Photo-generated dinuclear {Eu(II)}2 active sites for selective CO2reduction in a photosensitizing metal-organic framework Nat. Commun. 2018, 9, 3353.
16) Zheng, H.; Du, M-H.; Lin, S-C.; Tang, Z.-C.; Kong, X.-J.;* Long, L.-S.;* Zheng, L.-S.Assembly of Wheel-Like Eu24Ti8 Cluster under the Guidanceof High Resolution Electrospray Ionization Mass SpectrometryAngew. Chem. Int. Ed. 2018, 57, 10976 –10979.
17) Zheng, X.-Y.; Kong, X.-J.;* Zheng, Z.;* Long, L.-S.;* Zheng, L.-S. High-Nuclearity Lanthanide-Containing Clusters as Potential MolecularMagnetic Coolers Acc. Chem. Res. 2018. 51, 517−525.
18) Zheng, X.-Y.; Jiang, Y.-H.; Zhuang, G.-L.; Liu,D.-P.; Liao, H.-G.; Kong, X.-J.;* Long, L.-S.;* Zheng, L.-S. A Gigantic MolecularWheel of {Gd140}: A New Member of the Molecular Wheel Family. J.Am. Chem. Soc. 2017, 139, 18178−18181.
19) Zheng, X.-Y.; Zhang, H.; Wang, Z. X.; Liu, P. X.;Du, M. H.; Han, Y. Z.; Wei, R. J.; Ouyang, Z. W.; Kong, X.-J.;* Zhuang,G.-L.;* Long, L.-S.;* Zheng, L.-S. Insight into Magnetic Interaction in Monodisperse Gd12Fe14Metal Cluster. Angew. Chem. Int. Ed. 2017, 56, 11475−11479.
20) Kong, X.-J.; Lin, Z.; Zhang, Z.-M.; Zhang, T.; Lin, W. B.* Hierarchical Integration of Photosensitizing Metal–Organic Frameworks andNickel-Containing Polyoxometalates for Efficient Visible-Light-Driven HydrogenEvolution. Angew. Chem. Int. Ed. 2016, 55, 6411–6416.
21) Liu, D.-P.; Lin,X.-P.; Zhang, H.; Zheng, X.-Y.; Zhuang,G.-L.;* Kong, X.-J.;* Long, L.-S.;* Zheng, L.-S. Magnetic Properties of a Single-Molecule Lanthanide–Transition-MetalCompound Containing 52 Gadolinium and 56 Nickel Atoms Angew. Chem. Int. Ed. 2016, 55, 4532–4536.
22) Peng,J.-B.; Kong, X.-J.;* Zhang, Q.-C.; Orendáč, M.；Prokleška, J. Ren, Y.-P.; Long, L.-S.;* Zheng, Z.-P.; Zheng, L.-S. Beauty,Symmetry, and Magnetocaloric Effect-Four-Shell Keplerates with 104 LanthanideAtomsJ. Am. Chem. Soc.2014, 136, 17938-17941.
23) Zhan, W.-W.; Kuang, Q.;* Zhou, J.-Z.; Kong, X.-J.;* Xie, Z.-X.;Zheng, L.-S. Semiconductor @ metal-organic framework core-shellheterostructures: a case of ZnO@ZIF-8 nanorods with selectivephotoelectrochemical response J. Am. Chem. Soc. 2013,135, 1926-1933.
24) Peng, J.-B.; Zhang, Q.-C.; Kong, X.-J.;* Zheng, Y.-Z.; Ren, Y.-P.; Long, L.-S.;* Huang, R.-B.; Zheng,L.-S. Zheng, Z.-P. High-Nuclearity 3d−4fClusters as Enhanced Magnetic Coolersand Molecular Magnets J. Am. Chem. Soc. 2012,134, 3314−3317.
25) Peng, J.-B.; Zhang, Q.-C.; Kong,X.-J.;* Ren, Y.-P.;Long, L.-S.;* Huang, R.-B.; Zheng, L.-S. Zheng, Z.-P. A 48-Metal ClusterExhibiting a Large Magnetocaloric Effect. Angew. Chem. Int. Ed. 2011, 50, 10649–10652.
26) Zhao, H.-X.;# Kong, X.-J.;# Li, H.;#Jin, Y.-C. Long, L.-S.;* Zeng, X. C.;* Huang, R.-B.;Zheng, L.-S. Transition from one-dimensional water to ferroelectric ice withina supramolecular architecture Proc. Natl. Acad. Sci. USA. 2011.108, 3481-3486.
27) Kong, X.-J.; Long, L.-S.;*Zheng, Z.-P.* Huang, R.-B.; Zheng, L.-S. Keeping the Ball Rolling:Fullerene-like Molecular Clusters Acc. Chem. Res. 2010.43, 201-209.
28) Kong, X.-J.; Wu, Y.-L;Long, L.-S.;* Zheng, L.-S.; Zheng, Z.-P.* A 60-Metal Sodalite Cage Constructedby 24 Vertex-sharing [Er4(μ3-OH)4]Cubanes J. Am. Chem. Soc. 2009, 131, 6918-6919.
29) Kong, X.-J.; Ren, Y.-P.;Chen, W.-X.; Long, L.-S.;* Zheng, Z.-P.;* Huang, R.-B.; Zheng, L.-S. A Four-Shell, Nesting Doll-like 3d–4fCluster Containing 108 Metal Ions Angew. Chem. Int. Ed. 2008, 47, 2398-2401.
30) Kong, X.-J.; Ren, Y.-P.;Long, L.-S.;* Zheng, Z.-P.;* Huang, R.-B.; Zheng, L.-S. A Keplerate Magnetic Cluster Featuring anIcosidodecahedron of Ni(II) Ions Encapsulating a Dodecahedron of La(III) Ions J. Am. Chem. Soc., 2007, 129, 7016-7017
